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Ammonium Fluozirconate

(NH₄)₂ZrF₆ — Ammonium Hexafluorozirconate

Description

Ammonium fluozirconate is a key component in next-generation chrome-free conversion coatings for aluminium and steel. As environmental regulations tighten globally, zirconium-based surface treatments are replacing chromate processes.

Applications

  • Metal Surface Treatment
  • Chrome-Free Coatings
  • Ceramic Glazes

Quick Facts

CAS Number16919-31-6
Formula(NH₄)₂ZrF₆
CategoryFluozirconates
FormWhite crystalline powder
Item Code1005

Safety & Transport

Class 6.1

Safety Data Sheet (SDS) available on request. Contact us for regulatory documentation.

Packaging

25 kg HDPE bags

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Product Reference Data

Chemistry & Physical Properties

Ammonium hexafluorozirconate, formula (NH4)2ZrF6, formula weight 241.21 g/mol. White crystalline solid, monoclinic crystal system. Density 2.45 g/cm3. Decomposes above 350°C, releasing ammonia and HF. Solubility in water approximately 27 g/100mL at 25°C. The ZrF6 2- anion is octahedral and coordinatively saturated.

Standards & Specifications

Conversion-coating grade conforms to internal specifications of major automotive paint-shop chemical suppliers. Reference industry standards: ASTM D5894 (cyclic salt fog/UV exposure for paint pretreatment), ISO 12944 (corrosion protection by paint systems). Pharmacopeial grades not commonly specified. Nuclear-grade variants with controlled hafnium content (< 100 ppm) available on dedicated production runs.

Regulatory & Transport Profile

CAS 16919-31-6. UN 2923 — Class 8 (Corrosive), PG III. GHS pictograms: GHS05 (corrosive), GHS07 (harmful). REACH registered (EC 240-973-0). TSCA listed. Releases ammonia and HF on thermal decomposition — important for thermal-process design and ventilation requirements. RoHS — zirconium compounds are not restricted.

Available Grades

GradeTypical SpecificationCommon Use
Industrial95-98%Automotive pretreatment, conversion coating
Standard HfHf 1-2%General industrial use
Nuclear-GradeHf < 100 ppmNuclear research feedstock
Custom Particle SizeApplication-specificSpecific bath formulators

Product Information & Resources

Frequently Asked Questions

Why does hafnium content matter?
Hafnium has a very high neutron absorption cross-section. For nuclear research and reactor-grade applications, it must be removed; for normal industrial use, hafnium content (typically 1-2%) is acceptable.
Is this REACH compliant for automotive use?
Yes — it is registered under REACH (EC 240-973-0) and is the regulatory-friendly chrome-free pretreatment chemistry used by all major automotive OEMs.
How is it stored?
In moisture-tight HDPE bags or fiber drums, away from strong bases. Avoid contact with strong acids, which would release HF.
Available in custom particle size?
Yes — particle-size distribution can be tuned for specific bath-formulation requirements. Lead time for custom lots is typically 4-6 weeks.

Product Name in Other Languages

中文 (Chinese)
六氟锆酸铵
日本語 (Japanese)
六フッ化ジルコン酸アンモニウム
한국어 (Korean)
육플루오로지르콘산 암모늄
Español (Spanish)
Hexafluorozirconato de amonio
العربية (Arabic)
سداسي فلوروزركونات الأمونيوم
Русский (Russian)
Гексафтороцирконат аммония
Português (Portuguese)
Hexafluorozirconato de amónio

Authoritative References & External Data Sources

For peer-reviewed property data, regulatory listings, and structure verification:

PubChem (CID 24831) →CAS Registry — 16919-31-6 →ECHA / REACH →ChemSpider →ChemBK →